A Mn 36Ni 4 'loop-of-loops-and-supertetrahedra' aggregate possessing a high S T= 26 ± 1 spin ground state

Charalambous, Maria; Moushi, Eleni; Papatriantafyllopoulou, Constantina; Wernsdorfer, Wolfgang; Nastopoulos, Vassilios; Christou, Georgios; Tasiopoulos, Anastasios J.

doi:10.1039/c2cc30654a

A Mn 36Ni 4 'loop-of-loops-and-supertetrahedra' aggregate possessing a high S T= 26 ± 1 spin ground state

Author(s)

Charalambous, Maria

Moushi, Eleni

European University Cyprus

Papatriantafyllopoulou, Constantina

Wernsdorfer, Wolfgang

Nastopoulos, Vassilios

Christou, Georgios

Tasiopoulos, Anastasios J.

Abstract

The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a Mn III 28Mn II 8Ni II 4 molecular aggregate which consists of two Mn III 8Ni 2 loops and two Mn III 6Mn II 4 supertetrahedral units and displays a high ground spin state value S T = 26 ± 1.

Part Of

Chemical Communications

Issue

44

Volume

48